Synthesis and Properties of Polyguanamines Containing <i>N</i>-Phenylmelamine Units

The polyguanamines were prepared by the polymerization of bis[N-(2-anilino-4-chloro-1,3,5-triazine)yl]-4,4’-oxydianiline (Bis(ACT)) with α,ω-alkylene diamines such as 1,12-diaminododecane, 1,10-diaminodecane and 1,8-diaminooctane. NMR analysis Bis(ACT) resulting showed that hydrogen bonds cause between triazine adjacent anilino units. have good solubility in typical organic solvent. Temperatures where 5% weight losses occur under N2 flow are rage 435-449℃. glass transition temperatures (Tg) range 133-156℃. Almost colorless flexible films successfully a solution casting method. optical transmittance was high 80% at 400 nm. Furthermore, exhibited reflective index around 1.67.